Abstract




 
   

IJE TRANSACTIONS C: Aspects Vol. 31, No. 6 (June 2018) 863-869   

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  USING THE GENETIC ALGORITHM BASED ON THE RIEDEL EQUATION TO PREDICT THE VAPOR PRESSURE OF ORGANIC COMPOUNDS
 
H. Bakhshi, A. Dehghani and S. Jafaripanah
 
( Received: November 01, 2017 – Accepted in Revised Form: February 08, 2018 )
 
 

Abstract    In this paper, a genetic algorithm (GA) has been used to predict the vapor pressure of pure organic compounds based on Riedel equation. Initially, the coefficients of Riedel equation were optimized. Then, a new term was added to the original Riedel equation to reduce error of the model in prediction of vapor pressures of pure materials. 110 components at two different pressures (10 and 100 kPa) were chosen to investigate the capability of mentioned models. Absolute average relative deviation percent (AARD %) was reported for 40 components as testing materials to compare the calculated results of two models with experimental data. Results showed that the exerted modification on Riedel equation decreases the errors in prediction of vapor pressures of chemical components.

 

Keywords    Genetic Algorithm, Vapor Pressure, Riddle Equation, Clapeyron, Optimization

 

چکیده    در این مقاله از الگوریتم ژنتیک برای پیش بینی فشار بخار ترکیبات آلی خالص بر پایه معادله ریدل استفاده شده است. در این کار ابتدا با انتخاب 110 ماده مختلف به بهینه سازی ضرایب معادله ریدل برای کاهش خطای ناشی از این روش در پیش بینی فشار بخار برای فشارهای 100 و 10 کیلوپاسکال پرداخته شده است. همچنین با افزایش یک ترم به معادله اصلی و ارائه معادله کلی جدید بر پایه روش ریدل، خطای ناشی از پیش بینی مقدار فشار بخار برای فشارهای100 و 10 کیلوپاسکال، کاهش داده شده است. پس از مشخص شدن معادله بهینه و معادله جدید، دقت معادلات با بررسی خطای حاصل از 40 ترکیب مختلف سنجیده شد. نتایج نشان داد که اصلاح اعمال شده بر معادله ریدل، خطاهای پیش بینی فشار بخار ترکیبات شیمیایی را کاهش می دهد.

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